It looks like something to do with the 'modes' has changed.
Prior to Monday I would have Timed Charge and Discharge enabled and setup for the Economy 7 tariff I'm on, charging the battery as needed overnight, then switching over to battery just before the 'day rate' kicked in. That's how I'd reset it after the bug that caused the battery not to charge was resolved, but then it wasn't charging the battery with excess solar.
It now does charge the battery with excess solar, but only in Eco mode, if I set something in the Timed Discharge tab, it then just exports any excess.
How do I set this up so that it uses grid power for the whole of the 'night rate' and battery power the rest of the time (as available), charging the battery with excess solar as Eco also seemed to switch over to battery as soon as it was charged to 100% last night, rather than at the end of the 'charging period'?