simondoyle To answer some of your questions:
The 5.2kW has a depth of discharge of 80%, which means it has a usable rating of 4.1kW - YES
The 8.2kW contains a pair of 5.2kW (total power 10.4kW) which again have a DoD of 80%, i.e. 2 x 4.1kW but are branded as an 8.2kW with 100% DoD. - Proabably Yes
Is there actually a 5.2 with 90% DoD? Does that constitute a v2 of the 5.2? (this is not mentioned on the factsheet, but I've seen it referenced in the forum) - Not as far as I am aware, but its possible its in "development"
I am pretty certain that the 8.2 and 9.5 are more or less the same batteries but have slightly different internal Battery Management Systems (BMS). With the 9.5 having a new/better version which therefore allows access to more of the total charge. There may be some slight differences externally, but will be negligible.
Essentially 8.2 is 10.4 @ 80% DoD, 9.2 is 10.4 @ 90% DoD
It's not quite as simple as being "stuck together" but they will use a standard Lithium Iron Phosphate Cell internally which is then connected to a BMS or multiple BMS to control the batteries Depth of Discharge, State Of Charge, Temperature, Balancing Voltages and many other processes.
2 x 5.2 or 1 x 8.2 (or 9.5) mostly its going to come down to space, location and additional wiring. We originally intended for our entire system to be installed in the Loft, but once the battery arrived there was no way anyone could lift 110kg into the loft.
Both the larger batteries (8.2 and 9.5) have unlimited cycle warranties. The 2.6 and 5.2 have 26MWh & 52MWh (or the equivalent of 10,000 cycles).
If you buy the combined system Solar Panels, Inverter & Batteries in one go you get all kit excluding VAT. So adding batteries at a later date will cost you more due to VAT plus installation (also + VAT).
Unless you are a single person living at home alone and working all day you will probably find that you need more than 5.2kwh over night. I would say you are looking at about 3.5ish-5kwh per person (but that's a generalisation). We are occasionally running out of battery now with a 9.2 with 3 adults and fully charging every night on cheap rate tariff.
If your interested in what the internals look like you can check out the content by Will Prowse in USA on Youtube
https://www.youtube.com/@WillProwse
Or The Off Grid Garage in Australia
https://www.youtube.com/@OffGridGarageAustralia