Presumably you have a GE 5kW hybrid inverter. Gen1 or Gen2?
Either way there are a number of parameters that have to be checked to ensure they do not exceed allowed limits.
1/ Max DC power = 6500 W
2/ Max DC voltage = 600 V
3/ MPPT voltage range = 120-550 V
4/ Max input current per string = 11.0 A
With 12 x 400W on 1 string, you certainly need to check the Voc does not exceed 600 V under worst case conditions (usually -10.0 C temperature).
You will need the data sheet for your exact model of solar panels.
If all the limits pass the test, then your inverter may have capacity for extra panels that provide up to 1700 W peak on your other roof, but do not take my word for it. 6500 - 4800 = 1700 W.
Normally the prospective installer carries out all the check calculations to ensure the inverter will not be overloaded.
1700 W peak would typically only be 4 x 425W panels on the 2nd string, which may have issues with the startup voltage of the inverter string (Gen1=100V, Gen2=150V). Again the panel data sheet is required for the relevant figures.
For panels on different aspects, you normally need an optimiser on every panel in order to cater for the changing shading/output over the course of the day. This would work out pretty expensive to retrofit on your existing panels as well as any new panels.