Things returned to normal once solar generation stopped and the battery started to discharge. Looks like the problem was indeed that the battery discharge figure was at 81W despite having been previously set to 3000W and confirmed. Still don't know if the set to 3000W had actually failed or it had worked and something later caused it to revert to 81W. Wish I had done a read shortly after setting to 3000W rather than the next day!
One interesting thing to come out of this ( and the reason I did not immediately spot what was going on) is the way the discharge limit works when Eco Mode is enabled and in operation. Rather than a flat line discharge or clipping at the set limit I was seeing quite a variation around the set limit both above and below. The discharge was varying between 37W and 138W which, given that the later read showed the limit was set to 81W, suggests that Eco Mode processing trumps the discharge limit. More of a "keep it down to about this level" rather than a "do not exceed under any circumstances".