I too am relatively new to Octopus tariffs and I initially selected Agile Outgoing to support my battery and solar set up. My incoming tariff is Cozy Octopus and I am comfortable with that, but once I installed predbat on my HomeAssistant appliance, I realised that Fixed Outgoing makes more sense for me, so I am in the prcess of switching to it.
My rationale behind initially choosing the agile export tariff was that the per unit export price was nice and high during peak periods, but in fact it is only worth exporting for about 3-4 hours per day. With a fixed-price export tariff, there are many more opportunities to export throughput the day and this more than compensates for the lower "peak" export prices.