Ok, lets add some detail. Dinorwig did and does have one or more machine spinning in air most of the time (more or fewer depending on expected need). This means that the units are motoring in the generating direction with the water supply cut off and the turbines running in air. Since the unit is already rotating and synchronised, there is no need to bring it up to speed when needed. 330MW per unit on standby is available merely by opening the penstocks. Less than 10 seconds.
The same response can be produced if one or more units are pumping to re-fill Marchlyn Mawr. In that case, the operators can shut the penstocks and vent the turbine to eliminate the pumping load.
It takes longer to go from pumping to generating because the units run in oposite directions for the two purposes. It was intended that the operators could, actually do this by careful opening of the penstocks to brake and re-accelerate the unit. Then synchronising it for generation.
My learned knowledge is some decades out of date and first hand experience was limited to taking the CEGB Barnwood inspectors around the fabrication shop when the generator pole piece endplates were being welded on and working next to the modified boring machine where the rotor shafts were being leveled and balanced. I was pretty exiting for a young man though. 😀