THALL On Flux this is the general flow:
02:00 - 05:00 Charge 100% SOC
05:00 - 16:00 Eco Mode + Timed Discharge enabled but because it's not Timed Discharge time slot it just acts like Eco Mode.
16:00 - 22:00 Timed Discharge slot which prevents the battery charging but doesn't dump battery to grid.
22:00 - 02:00 Eco Mode + Timed Discharge enabled but because it's not Timed Discharge time slot it just acts like Eco Mode.
I'm going to ignore Timed Export as that is a whole different kettle of fish, and is the main thing you'd need something like Octopus R&D to control, because Timed Export disables Eco Mode and Timed Discharge modes when it's enabled.
In the original scenario, this all works fine and Eco mode operation works outside of the Timed Discharge window as anticipated. Timed Discharge slot just prevents the battery from charging if it's within the configured time window for DC Discharge 1 timeslot.
I didn't want to drag this into a Flux specific issue too much because I don't think my timings or settings are causing this. I'm suspecting that it's getting confused as the daylight is coming in earlier and is almost getting light at 05:00 now, which seems to cause the BMS to conflict with itself as to whether it should charge the battery, or discharge to cover house load.
If it was my settings I wouldn't expect to see the battery fully taking over after 10-15 minutes like it does without issue, without any configuration changes.