MrBananas This thread might tease out some of the issues for you, particularly regarding the window for overnight rate ie that it's not long enough to charge a large battery with a 3kW inverter.
We purchased our solar system after electricity suppliers started to go bust and gas/electricity prices rocketed so we haven't been able to change from the variable rate tariff for electricity that we landed on when our supplier went bust. However, we do have a large array and two 5kW hybrids each with its own 8.2kWh battery. If the sun shines, the batteries are fully charged by mid to late morning and the EV can be topped up in the afternoon (when it's on the drive) after the washing has been put on. The batteries are usually still more than 50% charged by the time the PV starts to charge again the next day. We can easily ride out one day of poor PV production but two or more in succession puts us back onto the grid. The weather here in north Wales was not brilliant yesterday and it took all day to charge both batteries up to 100%. That said, our import from the grid has reduced from over 100kWh/week to less than 10kWh/week, and that's in February and March, having bought the EV in February. We haven't actually tried to reduce our consumption, in fact it has gone up because of the EV, but we have changed where the energy comes from.
Thinking about your ideas, you may struggle if you have both EVs charging overnight and you want to charge more than one battery. Assuming that each EV charger is 7kW, that's about 30A each; 60A overnight import. Depending on the supply from your DNO, you might be limited to a 60, 80 or 100A main fuse. Even a 100A fuse would only give an additional 10kW to charge your batteries. Of course, if you only have one EV charging, then the issue becomes easier to solve, but still difficult to ensure you can match your demand to the DNO supply. Using your existing FIT-array to charge your batteries during the day would ease the situation and should be readily done by ensuring that the new equipment charges the battery in preference to exporting to the grid. Whether there's enough sunlight/PV capacity and time overnight to do all that you need might take a bit more thought.